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Tantalum [Ta]
CAS-ID: 7440-25-7
An: 73 N: 108
Am: 180.9479 g/mol
Group No: 5
Group Name: Transition metals
Block: d-block  Period: 6
State: solid at 298 K
Colour: grey blue  Classification: Metallic
Boiling Point: 5731K (5458°C)
Melting Point: 3290K (3017°C)
Superconducting temperature: 4.47K (-268.68°C)
Density: 16.69g/cm3
Discovery Information
Who: Anders Ekeberg
When: 1802
Where: Sweden
Name Origin
From king Tantalus of Greek mythology.
 "Tantalum" in different languages.
Sources
Chiefly occurs in the mineral tantalite [(Fe, Mn) Ta2O6] and euxenite (as well as samarskite and fergusonite). Always found with niobium. Tantalum ores are mined in Australia, Brazil, Eqypt, Canada, Democratic Republic of Congo, Mozambique, Nigeria, Portugal, Malaysia and Thailand.
Around 840 tons are produced annually.
Abundance
 Universe: 8 x 10-5 ppm (by weight)
 Carbonaceous meteorite: 0.02 ppm
 Earth's Crust: 2 ppm
 Seawater: 2 x 10-6 ppm
Uses
Used to produce metals that have high melting points, are strong and have good ductility. Alloyed with other metals, it is also used in making carbide tools for metalworking equipment and in the production of superalloys for jet engine components, chemical process equipment, nuclear reactors, and missile parts. Because of its ductility, tantalum can be drawn into fine wires or filaments, which are used for evaporating metals such as aluminium.
Tantalum pentoxide is used in capacitors, condensers, cutting tools, vacuum tube filaments and in camera lenses to increase refracting power. Because it is totally immune to the action of body liquids and is nonirritating it is widely used in making surgical appliances.
History
Tantalum was discovered in Sweden in 1802 by Anders Ekeberg and isolated in 1820 by Jöns Berzelius. Many contemporary chemists believed niobium and tantalum were the same elements until 1844 and later 1866 when researchers showed that niobic and tantalic acids were different compounds. Early investigators were only able to isolate impure metal and the first relatively pure ductile metal was produced by Werner von Bolton in 1903. Wires made with tantalum metal were used for light bulbs until tungsten replaced it.
Its name is derived from the character Tantalus, father of Niobe in Greek mythology, who was punished after death by being condemned to stand knee-deep in water with perfect fruit growing above his head, both of which eternally tantalized him - if he bent to drink the water, it drained below the level he could reach, and if he reached for the fruit, the branches moved out of his grasp. This was considered similar to tantalum's general non-reactivity-it sits among reagents and is unaffected by them. The English word tantalize was named after Tantalus, and tantalum was named after the tantalizing problems posed by the inertness of the element and its compounds.
For many years, the commercial technology for separating tantalum from niobium involved the fractional crystallization of potassium heptafluorotantalate away from potassium oxypentafluoroniobate monohydrate, that had been discovered by Marignac in the 1860s. The method has been supplanted by solvent extraction from fluoride-containing solutions.
Notes
The metal is renowned for its resistance to corrosion by acids; in fact, at temperatures below 150°C tantalum is almost completely immune to attack by the normally aggressive aqua regia. It can only be dissolved with hydrofluoric acid or acidic solutions containing the fluoride ion and sulfur trioxide (SO3).
Previously know as tantalium.
Hazards
There is some evidence that tantalum compounds can cause tumors. Its metal dust is a fire and explosion hazard, and may also act as an irritant.
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